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SECTION 3: HAZARDS IDENTIFICATION
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*******************Emergency*******************
*******************Overview******************
CAUTION!
Notice:
May causes skin and eye irritation.
May causes irritation of the respiratory tract.
Be harmful if swallow.
*********************************************
SKIN CONTACT :
May causes skin irritation on prolonged or repeated exposure. Not considered toxic by skin absorption. Avoid
contact. Wash thoroughly after handling.
EYE CONTACT :
May causes eye irritation on prolonged or repeated exposure. Avoid contact. Wear eyewear.
INHALATION :
May cause irritation to upper respiratory tract .
INGESTION :
Do not take internally. Not considered toxic by animal tests, but would be harmful if swallow.
CHRONIC EFFECTS :
None known .OTHER HEALTH EFFECTS :
Polyethylene amines are suspected mutagens.
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SECTION 4 : FIRST AID MEASURES
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SKIN CONTACT :
Flush with plenty of water. Then wash the skin completely with the suds and branch of water. Removing
contaminated clothing .
EYE CONTACT :
Flush with plenty of water at least 15 minutes. Call a physician .
INHALATION:
Move to fresh air . If symptoms persist , consult a physician .
INGESTION :
Induce vomiting . Give a large quantity of milk or water . Call a physician.
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SECTION 5 : FIRE FIGTING MEASURES
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General fire hazards: Steam and air to form explosive mixture. Open flame, high heat may cause burns. Can
cause strong reaction with Oxidizing agent. Let out poisonous gases when burns.
AUTOIGNITION TEMPERATURE: Not Determined
RECOMMENDED EXTINGUISHING MEDIA :
Carbon dioxide , foam , sand, water spray to reduce the temperature
SPECIAL FIRE FIGHTING PROCEDURES :
When fire fighting , wear full protective equipment including self-contained breathing apparatus .
UNUSUAL FIRE OR EXPLOSION HAZARDS :
May produce hazardous fumes or hazardous decomposition products .
HAZARDOUS COMBUSTION PRODUCTS :
Irritating and toxic gases or fumes may be released during a fire .
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SECTION 6 : ACCIDENTAL RELEASE MEASURES
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STEPS TO TAKE IN CASE OF SPILL OR LEAK :
Using adequate protective equipment , add sand and soid to absorb spill ( if large spill , first dike to contain ) .
Pick up and containerize . If the quantity is large ,dig a hold to collect.
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SECTION 7 : HANDLING AND STORAGE
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The workplace must be well ventilated. Use explosion-proof equipment and tools. Suggest that staff wear the
filter type respirator, rubber gloves.
Keep away from fire and heat source.Keep container tightly closed when not in use . Store in a cool(lower than30ºC) and dry location .Avoid sunlight.
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SECTION 8 : EXPOSURE CONTROLS/PERSONAL PROTECTION
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EYE PROTECTION :
Chemical goggles
SKIN PROTECTION :
Rubber or plastic gloves .
RESPIRATORY PROTECTION :
Use the filter type respirator.
OTHERS:
No smoking, no eating, not drinking in the working place.
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SECTION 9 : PHYSICAI and CHEMICAL PROPERTIES
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PHYSICAL STATE : Liquid
APPEARANCE : Turbid liquid
ODOR : Excitant odour
ODOR THRESHOLD : NOT Determined
PH : NOT Determined
MELTING POINT : N/D Deg C
BOILING POINT : >110 Deg C
IGNITION POINT : >400 Deg C
SPECIFIC GRAVITY : 0.980
SOLUBILITY IN WATER : slight ( 0.1 to 1% )
PERCENT VOLATILES (by wt.) : 0 at 40 Deg C.
VAPOR DENSITY : NOT Determined
VAPOR PRESSURE : NOT Determined
EVAPORATION RATE (N-BUTYL ACETATE=1) : NOT Determined
VOC CONTENT (EPA Method 24) : 0.0%
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SECTION 10 : STABILITY AND REACTIVITY
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STABILITY : Normally stable
HAZARDOUS POLYMERIZATION : Will not occur .
INCOMPATIBLE MATERIALS:
Strong acids , oxidizers.
CONDITION TO AVOID :
May produce hazardous fumes or hazardous decomposition products.
HAZARRDOUS DECOMPOSITION PRODUCTS :
Upon decomposition , this product emits carbon monoxide , carbon dioxide ,
and/or low molecular weight hydrocarbons.
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SECTION 11: TOXICOLOGICAL INFORMATION
-----------------------------------------------------------------------------------------------------------------------------------------TYPE OF STUDY
RESULTS
SPECIES
EYE IRRITATION
68.8 (Scale 0-110)
Rabbit
ORAL LD (50)
>8.0 g/Kg
Rat
SKIN IRRITATION
3.4 (Scale 0-8 ) Rabbit
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SECTION 12 : ECOLOGICAL INFORMATION
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ECOLOGICAL TOXICITY:
Not Determined
ENVIRONMENTAL FATE :
Not Determined
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SECTION 13 : DISPOSAL CONSIDERATIONS
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This product , if disposed as shipped , is not a hazardous waste as specified in 40 CFR 261 . Consult state or local
officials for proper disposal method .
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SECTION 14 : TRANSPORTATION INFORMATION
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PROPER SHIPPING NAME : Not regulated for nonbulk highway transportation
UN/NA : N/A
DOT HAZARD CLASS : NOT Determined
DOT HAZARDOUS MATERIALS : Not Applicable
EMERGENCY RESPONSE GUIDE NUMBER : Not Determined
PACKAGING GROUP : Not Determined
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SECTION 15 : REGULATORY INFORMATION
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TSCA INVENTORY STATUS :
This product and/or all of its components are included on the TSCA
Inventory of chemical substances .
TSCA 12(b) COMPONENTS :
None
SARA 311/312 HAZARD CATEGORIES : Acute
SARA 313 TOXIC CHEMICALS :
None
SARA 302 EXTREMELY HAZARDOUS SUBSTANCES :
None
CERCLA HAZARDOUS SUBSTANCES :
None
CALIFORNIA PROPOSITION 65 COMPONENTS :
None
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SECTION 16 ; OTHER INFORMATION
-----------------------------------------------------------------------------------------------------------------------------------------Disclaimer:
This information is provided without warranty. The information is believed to be correct. This information
should be used to make an independent determination of the methods to safeguard workers and the
Product Description
SECTION 1: CHEMICAL PRODUCT and COMPANY IDENTIFICATION
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PRODUCT NAME :Polyurethane Adhesives
PRODUCT DESCRIPTION : Polyurethane Adhesives
MANUFACTURER:Guangzhou Daya New Chemical Materials Co., Ltd
Unit 1701B, No.120 Huangpu Avenue West, Tianhe District, Guangzhou, China
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Packaging & Shipping